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A lot of folks don't have the old knowledge that wetted ash burns you. It's actually the Arabic base of the word "alkali" and was historical common knowledge that we've lost. How bad it can be depends on the plant, but there's cases of people using popular ash and occluding it in folk remedy and getting pretty deep scarring burns. It's what we used to use to tan leather and make soap, after all.
Edit: Sometimes it results in pretty funny incidents though:
https://www.bbc.com/news/world-europe-26478900 (the chemistry in this article is completely out of wack. Generally it's potassium carbonate that you're creating with ash. You'd need to add slaked lime [lime dissolved in water, calcium hydroxide] to potash/potassium carbonate to make potassium hydroxide and calcium carbonate [chalk]).
https://www.ucanews.com/news/philippine-bishop-orders-probe-into-ash-wednesday-burns/81551
https://www.reddit.com/r/Catholicism/comments/7xia9n/help_my_church_added_too_much_water_to_the_ash/
https://www.foxnews.com/lifestyle/ash-wednesday-worshipers-in-colombia-hit-by-mysterious-burning-rash-on-forehead
What a mystery. And it only seems to happen in churches that use water for ash wednesday, never oil.