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Yeah the mask and timing is what caused that one prisoner to be in so much suffering since he knew it was going to happen imminently so he held his breath.
If it were done gradually over a period of like 30 minutes, he likely wouldn't have noticed and just drifted into unconsciousness.
Or put the mask on then switch it to N2 without him knowing when.
A lot more difficult to do without him noticing and the "feared" mask on his face and potential to vomit into the mask would still be an issue.
Yeah the room option is better in that regard.
It would need to have some hardware interlocks engineered though for safety reasons. After turning on the gas, you won't be able to physically open the door until the ventilation system removes the nitrogen after the execution.
You could do that although N2 gas is not that dangerous. Just opening a door to a well ventilated room will get rid of the gas. It is not poisonous or anything. Its not like you are doing this every week that you get lax about procedure.