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From your description, this sounds a lot like how double/triple pane windows work, or like a Trombe wall. Although a Trombe wall is meant to heat a home, vents could be used to take advantage of convection currents that shed the heat away from the house.
That said, this wouldn't necessarily be cooling per-se, but would be avoiding heat gain. And at that point, any material that's loosely coupled to then house would be equally effective, like a wall with studs 24" (60 cm) apart rather than the USA standard of 16" (40 cm).
In fact, this is how some homes with massively overhanging roofs manage to passively keep themselves manageable in the summer, since the overhang blocks direct sunlight from reaching the walls and windows at summer's high noon, but lets light in when the sun is lower in winter. Soffit vents let convection currents flow up the inside of the roof, exiting at a ridge vent. So the idea is sound and already deployed in relevant climates.